Tải bản đầy đủ - 0 (trang)
IV. Frequency Distribution of Minerals in Soils in Relation to Chemical Weathering

IV. Frequency Distribution of Minerals in Soils in Relation to Chemical Weathering

Tải bản đầy đủ - 0trang

CHEMICAL WEATHIGRINO OF MINERALS I N SOILS



259



Regions. Although the early stages of chemical weathering occur most

extensively in regions of cool climates, early stages of weathering occur

also in warm tropical and equatorial regions. The difference lies largely

in the time during which the early stage minerals can persist under conditions of widely different intensity of weathering. Feldspars can and

do occur in the finer fractions of some soils in the tropics but remain

only for a relatively short time on exposure to high rainfall and high

temperature. Thus Tamura (1951) found feldspar in the silt and coarse

clay of the surface horizon of the Naiwa soil family, which is classified

as a Ferruginous Humic Latosol. This finding suggests a relatively

recent deposition of minerals over the surface of the site of the profile

studied.

The youthful soils in the tropical regions are formed on lava, volcanic

ash, or sedimentary rock. The initial soil development depends to a large

extent on the amount of annual precipitation and on the susceptibility

of the rock to decomposition. I n the asid regions, the soils are likely to

be of the Red Desert group. These soils show evidence of very little

mineral weathering. According to Cline ct aE. (1953), the minerals

of the parent rock are dominant in soils formed under such a climate. In

general, weathering is so rapid in tropical areas that wherever there is

an appreciable amount of rainfall, the parent rock weathers rapidly to

minerals of the intermediate or advanced stages of weathering.

b. Saline Stage of Weathering (Stage 1 ) . The occurrence of soluble

salts, including gypsum, characterizes the mineralogy of soils in the saline

stage of weathering. Polders clay reclaimed from the sea in the Netherlands and saline soils in arid regions best exemplify this stage. The

presence of ferrous sulfide and its hydrates in poorly drained “gyttja”

soils of north Sweden and Finland has been studied by Wiklander and

Hallgren (1949) and Wiklander et al. (1950a, 1950b) and earlier by

Naumann (1918). The sulfide in the presence of air changes to sulfur,

and then slowly to sulfate, whereupon a very acid reaction develops.

Surface crusts of sulfates form when the sulfide content has been high.

The strong acidity causes the rapid weathering of minerals present. The

occurrence of up to 30 per cent of gypsum in certain horizons of a

tropical soil derived from shale is reported by Rodrigues and Hardy

(1947), and 14 per cent of gypsum was reported in a Brown Desert soil

of China (Hseung and Jackson, 1952).

c . Calcareous Stage of Weathering (Stage 2). Content of calcite,

dolomite, aragonite, siderite, and other moderately insoluble carbonates

characterizes soils of the calcareous weathering stage. The most frequent

Occurrence is of calcite, CaC03, in the depositional horizon of pedocals

(Marbut, 1935). This horizon marks the average depth of penetration



260



M. L. JACKSON AND



a.



DONALD SHERMAS



of soil moisture in soils of the arid regions. The identity of the deposited

carbonates in this type of zone as the mineral calcite has been noted in

several laboratories (Jackson et al., 1948).

Occurrence of about 10 per cent of calcite in the A horizon of Desert

and Chestnut soils of China was reported by Hseung and Jackson (1952).

Walter Fitts found up to 75 per cent of calcite in Minatare soil of

Nebraska, and Gt. A. Bourbeau noted calcite and dolomite crystals formed

in organic fragments in the A horizon of a Podzol of Wisconsin (reported

in Jackson et d.,

1948). Jenny (1941) showed the removal of calcium

carbonate from soils as a function of time ranging from 250 to 1000

years.

In tropical areas having a very strong and long dry season, a calcareous crust forms in the soil. Vageler (1933) and Charles (1948) describe

the formation of the calcium carbonate crusts in tropical soils. The

latter refers to it as a “calcareous carapace.”

Sherman (1937) and Sherman and Thiel (1939) noted the occurrence

of dolomite pedogenically formed in the Ulen and Bearden soils in the

Red River Valley of Minnesota. The occurrence of dolomite in this area

is associated with a high content of magnesium salts in the soil. Although the exact mechanism of the process has not been established, the

evidence indicates that the calcium carbonate is altered to dolomite by

magnesium sulfate with concurrent deposition of concretiong of gypsum.

Sherman et aE. (1947) found pedogenic dolomite in the soils of the Dark

Magnesium Clays of the Hawaiian Islands. These soils receive seepage

waters from weathering basalts of higher elevations. These seepage

waters are rich in magnesium salts.

&. Ferromagwsian a d Peldspw Btages of Wea.theri.ng f8tages 3, 4,

and 5 ) . The occurrence in the fine fractions of easily weathered minerals,

including ferromagnesian and f eldspathic minerals, characterizes soils

in which chemical weathering is in the early stages. Colloidal feldspars

have been termed “rock flour’’ and are chiefly the products of physical

weathering, particularly the product of grinding by glaciers, As in the

case of calcic minerals in soils of stage 2, the colloidal ferromagnesian

and feldspar minerals can only be present as a residue from relatively

low intensity and short time of weathering because they have a high

weathering capacity factor. They occur commonly in silt and sand (low

surface capacity factor).

The colloid (particles less than 0 . 2 ~in diameter) of Abitibi silt loam

C horizon of the northern Quebec locality was approximately 50 per cent

feldspars (stage 5) of the andesine-albite series (Ja-ckson et d.,1948).

Ten to fifteen per cent of amphibole and ferromagnesian chlorite (stage

4) were present, as shown by their characteristic diffraction lines. Some



CHEMICAL WEATHERING OF MINERALS IN SOILS



261



quartz and mica (stages 6 and 7) made u p the remaining p a rt; the mineral composition thus represented a distribution curve centered a t stage

5 (Jackson et al., 1948, Fig. 2). The coarse clay (particles 0.2-2p) has

more chlorite and amphibole but was otherwise similar.

Rideau clay soil, B horizon, from the southern Ontario locality showed

abundant (40 per cent) feldspars in the fine colloid as well as in the

coarse clay, but had much (30 per cent) quartz (stage 6) and less ferromagnesian minerals (Jackson e t al., 1948). Similar analyses were obtained of the fine and coarse clay fractions of St. Rosalie and St. Damase

soils (A horizons) of southern Quebec; 20-35 per cent of the fine colloid

(particles less than 0 . 2 ~ ) was andesine-albite series feldspars. It is

interesting to compare the weathering in these soils, in which stages 3-5

are disappearing a t the age of 5000-10,000 years, to that in soils reported

by Jenny (1941), in which stage 2 is disappearing a t the age of 250-1000

years. Jeffries et al., (1952) correlated the content of feldspars in soils

of Puerto Rico with the productivity rating of these soils.

Contrary to the belief of his time that soil clays were merely ground

up feldspars, quartz, and micas, Tamm (1920) concluded that clays of

soils were formed in part by chemical weathering. Disintegration of a

granite by grinding in cold water and in the presence of carbon dioxide

(Tamm, 1924) yielded a product 16 per cent of which he considered to

be formed by chemical weathering. From self-grinding of feldspars in

water suspension (Tamm, 1930), a size fraction of 0.2-2p was obtained;

ionic release from microcline yielded a p H of 10.7 and from oligoclase,

a p H of 11.1. With the latter, treatment of the suspension with acid

resulted in an irreversible exchange for bases and liberation of aluminum

ions throughout the p H range of 11-3. With the microcline, the exchange reaction with acid was reversible in the range 10.3-6, but was

similar to the oligoclase reaction below p H 6. Feldspar particles greater

than 2p i n diameter were little attacked. In later experiments Tamm

(1934) ground feldspars, micas, and other minerals in benzene suspension

to prevent chemical weathering, but a rise in p H and the release of

cations still resulted.



2. Soils of Intermediate Stages of Chemicd Weathering

Intermediate stages of chemical weathering of soil minerals are defined for convenience of discussion to include mineral weathering stages

6-9, inclusively, of the weathering sequence given in Section 11, lc. Soil

materials are to be considered here which contain quartz (stage 6), micas

(stage 7), interstratified 2 : 1 layer silicates and vermiculite minerals

(stage 8), and montmorin series minerals of the more stable species

(stage 9).



262



M. L. JACKSON AND 0. DONALD SHERMAN



a. Intermediate W>mtheringBtages O c c w 4% Soils of Both Cool amd

Warm Regions. Although the minerals of intermediate stages of weathering occur most abundantly in soils of the temperate regions, they also

occur in cold regions and in warm tropical and equatorial regions. The

occurrence of montmorin and kaolin in the cool climate of Norway,

Sweden, and Denmark seems to be limited to geological formations the

weathering product of which was protected from removal during the

Pleistocene period. The occurrence of minerals of intermediate weathering in warm regions is limited to areas of long intense dry seasons. Under these conditions the “tropical black soils” have developed, such as

the well-lmown “regur” soils of India, which are considered in connection with the occurrence of montmorin, below.

b. Quartz Stage of Weathering (Stage 6 ) . Quartz occurs generally

in small amounts in fine colloids of soils. It is relatively abundant in the

coarse clay fraction (particles 0.2-2p in diameter) of soils i n the glaciated

temperate and cold regions. I n the warmer regions, the quartz extinction function with size is a good measure of the degree of weathering of

the soil material, as has been brought out in connection with the size

function, Section 111, lc. It is to be kept in mind that quartz in the

coarse silt- and sand-size ranges is one of the most weathering-resistant

minerals, and thus the quartz stage 6 is limited to the finer size ranges of

particles.

Quartz colloids constituted 15 per cent of the fine colloid (particles

less than 0 . 2 ~ )of Abitibi silt loam, C horizon, in the northern Quebec

locality, and a similar percentage of this fraction of Rideau clay soil

of southern Ontario (Jackson et al., 1948). Quartz constituted about 5

per cent of the fine colloid of Miami silt loam of Wisconsin, but made up

15 per cent of the fraction from 0.08 to 0 . 2 of

~ this soil. In general about

one-third of the coarse clay fraction (particles 0.2-2p in diameter) of

soils in the North Central Region of the United States is made up

of quartz. Quartz is much less abundant in the coarse clay fraction of

many soils derived from mica-rich material. Quartz constitutes much of

the light-colored material in the A2 horizon of Podzols.

Small quantities of quartz, from 1to 5 per cent, are generally found

in the fractions less than 2p in Latosols of Hawaii (Tamura, et al., 1953).

Quartz made up 65 per cent of the fractions smaller than 5p in the

Yatzei “Podzol~’of China (Hseung and Jackson, 1952). This soil is

derived from cherty material which is unusually resistant to weathering.

It occurs in a region occupied normally by Latosols, and accordingly had

appreciable kaolin, hematite, and gibbsite.

c. Mica-Illite Stage of Weathering (Stage 7). The mica stage of

chemical weathering refers to the occurrence of a maximum in the dis-



CHEMIOAL WEATBERING OF MINERALS I N SOILS



263



tribution curve a t stage 7 (mica) when colloidal mineral percentage is

plotted against weathering stages of the weathering sequence presented in

Section 11, lc. The mica stage includes the mica having the typical 10-A.

diffraction spacing. Minerals of this stage have been termed illite, sericite-like, glimmerton, muscovite-like (Correns, 1936 ; Grim et al., 1937 ;

Maegdefrau and Hofmann, 1937), and are included as one portion of

the so-called hydrous micas. I n the interest of clarity, the interstratified

and other 2 : 1 layer silicates (of stage 8) which do not have a n observable 10-A. diffraction spacing and of which the interlayer spacings are

expansible to a lower degree than montmorin on solvation but which

still contain some nonexchangeable potassium, are excluded here and

presented as separate stage 8 (Section IV, 2d) below. Consistent with

this distinction, in introducing the term illite, Grim e t al. (1937) state

that the name was proposed “as a general term for the clay mineral

constituent of argillaceous sediments belonging to the mica group . . . it

is not proposed as a specific name.” It was distinguished from hydromica by the higher than usual water content of the latter.

Mica weathering is of first importance in connection with chemical

weathering of soil minerals because ( a ) micas occur in many kinds of

rocks, including those of igneous, metamorphic, and sedimentary origin,

( b ) micas constitute an important part of soil minerals in the colloid as

well as silt and sand fractions, and (c) micas are a n important weathering source of available soil potassium.

Grim (1942, p. 259) states: “It is likely that illite is formed infrequently in soils, whereas kaolinite and montmorillonite are commonly

formed by soil-forming processes. Illite is present in many soils, but is

usually as a remnant of the composition of the parent rock.” This observation on the residue mechanism for the occurrence of micas in soils

is borne out rather consistently by studies in many places. Feldspar on

weathering was found to yield dioctohedral micas (Stephen, 1952a,

195213) in part through the occurrence of mica as hydrothermal inclusions in the feldspar, but also through subsequent further crystallization

of mica.

According to Ross and Hendricks (1945) the occurrence of micas in

the western part of the Great Plains of the United States and also in the

glacial accumulations in the eastern section of the Plains is attributable

to the mica content of crystalline rock and reworked shales occurring in

these areas. The clay fractions of these soils therefore characteristically

contain more mica and less of the montmorin series than do those of the

Central Plains.

Alexander et al. (1939) reported dominance of hydrous mica in the

clay fraction of the Miami soil of Indiana. Micas i n smaller amounts



264



M. L. JACKSON AND Q. DONALD SHERMAN



were reported in soils throughout the eastern United States. They found

considerable mica in clay fraction of Carrington soil of Indiana and

Barnes soil of South Dakota, along with some montmorin. Several samples of Barnes, Moody, and similar soils of eastern South Dakota have

been examined by the senior author, and montmorin has dominated the

colloid fraction, less than 0.2p, whereas micas were important in the

coarse clay, 0.2-2y in diameter. Kelley and Dore (1938) reported mica

to be the chief colloidal constituent of the Hanford and San Joaquin

soils of California. Barshad (1946) likewise found mica to be the chief

colloidal constituent of Cayucos, Gleason, and Sheridan Prairie soils of

California.

Drosdoff and Miles (1938) noted a marked dispersion of mica-like

fragments by the action of hydrogen peroxide on a Desert soil from California. Alexander et al. (1939) noted 70 per cent of the 2 : 1 layer silicates in the colloid of this soil but did not differentiate the extent of

interlayer expansion. The colloid of less than 0.2y of this soil showed

strong and distinct lines for montmorin (18 A.) and mica in later studies

(Jackson and Hellman, 1942), whereas the coarse clay showed extremely

strong diffraction a t 10 A., indicative of mica. Evidently the mica had

weathered in part to montmorin. Illite predominated in the Mohave soil

of Arizona, but some montmorin occurred in it as well (Jackson and

Hellman, 1942; Buehrer et al., 1949). Bidwell and Page (1951) noted

a prevalence of micaceous minerals in soils of the Miami catena of Ohio

regardless of the drainage profile, ranging from the Bethel to the Brookston series. Small amounts of montmorin in association with large

amounts of mica were indicated by the thermal and X-ray diffraction

data on those fractions less than 0.5y in diameter. Micas were reported

in the percentage range of 20-40 per cent in the clay fraction of Grenada,

Sarpy, Atwood, and Norfolk soils (Coleman and Jackson, 1946) ; in combination with montmorin in several Ontario soils (Webber and Shivas,

1953) ; and in eleven Pedocal soils of China (Hseung and Jackson, 1952).

Illite was found to be abundant in the black soils of central France

(Collier, 1948). Illite was reported in Scotland (Mackenzie e t al., 1949)

in association with small amounts of montmorin, and the weathering

sequence feldspar-illite-montmorillonite was suggested. The presence

of a mica, identified as muscovite, was shown in Netherland clays (Baren,

1934), and the occurrence of mica with important amounts of montmorin

and a little kaolin was further shown (Favejee, 1939; Edelman et al.,

1939). Quartz was also an abundant constituent in the clay fraction.

Favejee (1949) found glauconite in the 0.5-y fraction of a soil in the

south Netherlands, and suggested this size for the upper limit of the clay

fraction. He further stated that the soil clay mica generally was not



CHEMICAL WEATHERING OF MINERALS IN SOILS



265



muscovite. Stremme (1951) reported an iron-illite i n a brown forest soil

in Germany. Illite appeared to be the principal silicate mineral in a

blue marl of Switzerland (Sigg and Steiger, 1950). The most extensive

soil colloidal mineral in Switzerland soils is illite (Iberg, 1953), but

numerous occurrences of montmorillonite-beidellite were observed. Nontronite was observed in weathered granite, and kaolin in old soils.

The prevailing clay-size minerals in the sticky clays in Norway are

hydrous mica, according to work reported by Brudal (1940) carried out

with the cooperation of H. G. Byers. More recent work by Rosenqvist

(1942, 1949) shows hydrous mica (illite) to make u p over half of the

fraction less than 2p in diameter in the sticky clays of Norway. Illite

was reported to be the most common minerd in soils of Sweden (Wiklander, 1950a, 1950b) in soils formed predominantly from varved glacial

and postglacial material. Quartz was found to be common and feldspars

detectable by X-ray diffraction. Some of the illites showed a strong

benzidine reaction, but others did not. As an exception to the above

trend, montmorin was found to be abundant in the till clays of Scandia.

Mica predominated in a dry sierran soil of the highlands of Ecuador

(Miller and Coleman, 1952). Evidence of mica was adduced in the

Humic Latosol of Hawaii on the basis of potassium content and allocation of hydroxyl and elemental analysis (Tamura et al., 1953).

d. Interstratified 2 : 1 Layer Silicate and Vermiculite Xtage of Weathering (ITtage 8). Interstratified 2: 1 layer silicate refers to the mixing

of layers of various layer silicates within a given single crystal. Layer

silicates which exhibit such mixing include the micas, vermiculites, montmorins, chlorites, pyrophyllites, and tales. The chief analytical manifestations of such interstratification are ( a ) a disruption of the basal

diffraction intensity spacings and (b ) production of intermediate properties as represented by elemental analysis and specific surface. Included

with weathering stage 8 also is vermiculite, which has more highly

charged layers than montmorin and consequently has less freedom of interlayer expansion. The properties of the layer silicates of this stage of

weathering (stage 8) are intermediate between those of micas (stage 7 )

and montmorin (stage 9 ). The stage 8 minerals have been termed “partially expanding” (Jackson and Hellman, 1942) and “ mica-intermediates” (Jackson et aZ., 1948), though they properly should be called

mica-montmorin intermediates, since the entire range of properties intermediate to micas and montmorins are found in different specimens. Because the vast and important differences in properties of these “partially

expanding” 2 : 1 layer silicates from those of the micas (including the

nonswelling illites having a 10-A. diffraction spacing), they clearly should

be placed in different weathering stages. The weathering mean (Sec-



266



M. L. JACKSON AND G. DONALD SHERMAN



tion 11, 2c) thus reflects the weathering change associated with a shift

from the true micas to the partially expanded materials by the shift of

the stage number from 7 to 8.

Gruner (1934, p. 561) stated that the potassium-bearing vermiculites

are made of interstratified layers of mica and vermiculite. Clark e t al.

(1937) noted the absence of a?basal diffraction spacing in soil clays which

did have the typical 4.45 A. line of layer silicates. They stated that soil

clay layer silicates might have to be taken as “entity” rather than being

characterized further as having a, definite structure. Hendricks and

Jefferson (1938) stated that mixtures of vermiculite with mica, chlorite,

pyrophyllite, and talc layers would be expected.

Alexander et al. (1939) suggested “mixed layers” (interstratification) of 2 : 1 layer silicate components on the basis of their X-ray diffraction analysis of several soil clays. Jackson and Hellman (1942)

noted a shift in the basal spacing of certain types of hydrous micas that

exhibited swelling properties and reported a 12-A. diffraction spacing

lrom these swelling types of hydrous micas. Hendricks and Teller

(1942) provided mathematical interpretation of the diffraction phenomena to be expected from interstratified materials. These functions were

presented graphically by Brown and MacEwan (1950). Nagelschmidt

(1944) also obtained intermediate basal spacings from glauconite and

from some illites. He concluded that the spacing indicated interstratification.

Ross and Hendricks (1945) pointed out the growing recognition of

the importance of interstratified 2 : 1 layer silicates, and the fact that

intermixtures of such minerals with the montmorins must be considered.

Montmorin clays “may contain mixed layers of mica, chlorite, talc, or

brucite and possibly other minerals of similar character. ’’ They also

state that “as beidellite is approached there is a decided tendency toward

formation of mixed layer type minerals containing potassium.’’ However, Gieseking (1949) stated that chlorite was the only interstratified

mineral conclusively shown to be present in soils.

A progressive weathering of biotite in soil, through mixtures of mica

and vermiculites, to vermiculite was reported by Walker (1949). He

states that “. . leaching of potassium from interlayer positions together

with replacement of iron in the interior of the silicate layers by magnesium and other ions from percolating waters reduce the attractive

interlayer forces and permit the entry of double layers of water molecules. This latter phenomenon spreads through the crystal layer by

layer, by giving first a mixed-layer structure in which increasing numbers

of layers become the vermiculite type. ” Increasing amounts of montmorin in association with mica weathering were found with decreasing



.



CHEMICAL WEATHERING OF MINERALS IN SOILS



267



particle size in soil materials weathered from granite (MacKenzie et al.,

1949). Walker (1950) reported both trioctahedral vermiculite and

montmorin formed from biotite. The diffraction maxima of weak, medium, and sometimes strong intensity at a spacing of 14.3 A. was found

(Pearson and Ensminger, 1949) for a number of soils including Norfolk,

Orangeburg, Ruston, G-reenville,Davidson, Decatur, and Hartsells. This

spacing did not increase to 18 A. with treatment with glycerol, indicating the presence of a vermiculite-like or chlorite-like mineral. Pearson

and Ensminger (1949) state: “ I n none of the clays included in the

present study is a characteristic hydrous mica line observed. ’ ’ Complex

interstratification of vermiculite, chlorite, mica, and montmorin has rccently been found in these Davidson and Hartsells (Heuvel and Jackson,

unpublished). Coleman et al. (1950) reported vermiculite and clay intermediates in Norfolk, Bladen, and Alamance soils of North Carolina

(strong 18 A. diffraction of montmorin also occurred with the Bladen

soil). A wide distribution of vermiculite and interstratified materials

was reported in soils of China (Hseung and Jackson, 1952). Occurrence

of vermiculite in an equatorial soil of South America was reported by

Barshad and Rojas-Cruz (1950).

Dyal e t al. (1951) reported on mineral content on a number of RedPodzolic soils from the southeastern United States. The results were

expressed as percentage of “inner-surface ” minerals, kaolin, quartz, and

gibbsite. The first category was determined as the percentage of inner

surface in ratio to that of “volclay ” (Wyoming bentonite). The inner

surface minerals comprised from about 10 to 60 per cent of the clay

fraction less than 2p in diameter. Kaolin comprised on the order of

15-30 per cent but as high as 50-60 per cent in a few samples. Quartz

and gibbsite were minor constituents. The classification given for inner

surface minerals includes minerals of the montmorin, vermiculite, and

expanding layers interstratified with mica minerals. The results concur

well with those reported by Coleman and Jackson (1946), if the weighted

average is taken by the two size fractions reported by the latter authors

in comparison with the results of the combined total clay (less than 2p)

by the former.

Bradley (1950a) concluded that mica layers occurred naturally as

‘ I discrete minerals, as random layered intergrowths of mixed species,

and as regular intergrowths of two complementary species.” Alternations of pyrophyllite and vermiculite interspaces were reported in rectorite, and thus the mineral contained scarcely any potassium, yet

consisted of 10- and 14-A. spacings interstratified (Bradley, 1950b).

Barshad (1948, 1950, 1951) showed that a slow exchange of niagnesium for the potassium of biotite results in the production of a 14-A.



268



M. L. JACKSON AND



a.



DONALD SHERMAN



spacing, and that the reaction is reversible by slow exchange with potassium. Depotassication of biotite through weathering would thus be expected to produce chlorite-like and vermiculite-like layer silicates. The

completion of removal of potassium along a given plane a t a rate ordem

of magnitudes faster than the rate of initiation of weathering along

such a plane was proposed (Jackson et al., 1952) as the reason for the

development of interstratification in the 2 : 1layer silicates. This effect

was termed the preferential weathering plane principle. It was further

proposed that alternate planes of micas axe more readily weathered, and

thus alternation of opened and closed interlayers was the result. Data

on clay materials were presented graphically to illustrate both 10-1810-18 and 10-14-10-14 sequences. Rolfe and Jeffries (1952) proposed

the use of the reversibility of the Barshad depotassication reaction with

attendant reversibility of the shift from 10-to 14-8.spacings as an index

of weathering and that it was applicable as a depth function.

Stephen (1952aJ states that the process of vermiculitization of biotite

can occur, either through mixed-layer biotite-vermiculite intermediate

stages (Kerr, 1930 j Wager, 1944 ; Walker, 1949) or through mixed-layer

biotite-chlorite and chlorite-vermiculite stages. Stephen and MacEwan

(1951) noted expansion of a chlorite in the range of 14-18 A. in the

presence of glycerol. This observation suggests a continuity of interstratification between chlorite, vermiculite, and montmorin.

Marel (1950a) has provided detailed X-ray diffraction data for the

various layer silicates that some have interlayer spacings greater than

those of micas. H e includes spacings for vermiculite, muscovite, illite,

and hydrated biotite. He distinguished the latter from hydrobiotite consisting of vermiculite and biotite layers (Oruner, 1934). Marel (personal communication) further calls attention to so-called metabentonites

(or mica intermediate or bravaisite, described by Mallaxd in 1878) in

some soils of France and in a clay bed in a coal mine a t Noyant d’Allier.

Some layer silicates with spacings of 14-15-A. were found not to contract

to 10-A. when treated with potassium, and Marel cautions again& a n

identification of the 14-A. spacing with vermiculite in the absence of

this potassium-contraction reaction.

Warder and Dion (1952) noted that potassium could be lked to the

extent of twice the cation exchange capacity of the 2 : 1 layer silicates

of soil colloids from Saska,tchewan. This indicated the presence of either

“ (a) a mixture of illite and montmorillonite or (b) a mineral intermediate in properties between illite and montmorillonite” (vermiculite S ) ,

They calculated that the colloids approached the composition of beidellite, but that the potassium content and composition indicated the



CHEMICAL WEATHERING OF MINERALS I N SOILS



269



“strong probability” of the presence of mixed layer minerals containing

potassium.

Mare1 and Bruijn (to be published), noted a layer silioate of 15.6-A.

diffraction spacing in abundance in vast areas of alluvial clays in the

Netherlands. They designate this by a new mineral name, “ammersooite,” but the spacing of 15.6-A. suggests interstratified 2 : 1layer silicates.

The decrease in intensity and broadening of angle of basal diffraction

of weathered micas occurring in soil colloids could arise in part from

increasing content of amorphous material as a diluent (Pennington and

Jackson, 1948; Gieseking, 1949), but the persistence of the (110) diffraction line out of proportion to the residual basal spacing, observed in

many laboratories (Clark et al., 1937; Jackson and Hellman, 1942), suggests randomness in the (OOL) sequence, with preservation of the layer

structure responsible for the (110) diffraction line. The principal

change accompanying mica weathering, a broadening of the angle of

basal diffraction as well as the decrease in basal diffraction intensity, is

believed (Jackson at al., 1952) to arise from the decreasing number of

layers having a 10-A. spacing in each zone not interrupted by vermiculite or montmorin interspaces, toward the minimum number for X-crystallinity.

On the basis of internal surface measurements together with water,

hydroxyl, and diffraction intensity data, the existence of interstratification in micaceous materials deficient in K was proposed (Jackson et al.,

1952) for a variety of materials including glauconite, illite, and a number

of so-called illitic soil clays. This conclusion may be summarized as

follows :

Mica + (expanded spacings) = (illite, sericite, glauconite, etc.) According to this concept, to speak of mixed structures of illite plus expanded spacings becomes redundant, since illite is characteristically

interstratified. Only when interstratification caused noticeable interruption of the 10-A. sequences and associated diffraction intensity had it

been generally recognized or emphasized in much of the literature.

Failure to recognize the interstratified nature of illite has led to considerable confusion in the interpretation of soil layer silicates. The

occurrence of some potassium in the material in the absence of potassium

feldspar, of course, proves the presence of some micaceous material.

Since the type illites vary greatly in the quantity of mica present (that

is, in their K content), materials which are considerably interstratified

with vermiculite and montmorin sometimes have been loosely designated

as illite. It now appears certain that analyses by means of diffraction, differential thermal, water and hydroxyl, and elemental analysis

techniques will permit a quantitative assignment of the components of



Tài liệu bạn tìm kiếm đã sẵn sàng tải về

IV. Frequency Distribution of Minerals in Soils in Relation to Chemical Weathering

Tải bản đầy đủ ngay(0 tr)

×